如何区分“hard metal ions” 与 “soft metal ions”如题

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如何区分“hard metal ions” 与 “soft metal ions”如题

如何区分“hard metal ions” 与 “soft metal ions”如题
如何区分“hard metal ions” 与 “soft metal ions”
如题

如何区分“hard metal ions” 与 “soft metal ions”如题
前者是硬金属离子,后者是软金属离子.
1958年S.阿尔兰德、J.查特和N.R.戴维斯根据某些配位原子易与Ag+、Hg2+、Pt2+配位,而另一些配位原子易与Al3+、Ti4+等配位, 将金属离子和配位原子分成a和b两类.a类金属离子包括碱金属、 碱土金属、高氧化数的轻过渡元素Ti4+、Fe3+、Cr3+和H+;b类金属离子包括较重的、低氧化数的过渡元素Cu+、Ag+、Hg2+、Pt2+.
所谓硬金属离子就是类金属离子,软金属离子就是b类金属离子.

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